Copper(II)/polyimide linked covalent organic framework as a powerful catalyst for the solvent‐free microwave irradiation‐based synthesis of 2,4,5‐trisubstituted imidazoles
نویسندگان
چکیده
Copper(II)/polyimide-linked covalent organic frameworks under solvent-free and microwave-assisted conditions have been used in an efficient one-pot protocol for the preparation of 2,4,5-trisubstituted imidazoles via benzil, aromatic aldehydes ammonium acetate. By applying microwave irradiation, three-component condensation provides safe operations, low pollution, quick access to products, easy set-up. As a result its reusability, catalyst can also be reutilized many runs without missing any activity.
منابع مشابه
nano-rods zno as an efficient catalyst for the synthesis of chromene phosphonates, direct amidation and formylation of amines
چکیده ندارد.
Targeted synthesis of a porous borazine-linked covalent organic framework.
The first microcrystalline borazine-linked polymer, BLP-2(H), has been synthesized. BLP-2(H) crystallizes into 2D sheets that stack in an eclipsed AA fashion, has high thermal stability (∼420 °C) and high porosity (SA(BET) = 1178 m(2) g(-1)) and it can store up to 2.4 wt% of hydrogen at 77 K and 15 bar with isosteric heat of adsorption of 6.8 kJ mol(-1).
متن کاملMagnetic Fe3O4 nanoparticles as a highly efficient catalyst for the synthesis of imidazoles under ultrasound irradiation
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Nano TiO2 supported on SiO2 (Nano TiO2@SiO2) as a solid Lewis acid, was described to be an effective and reusable catalyst for one-pot three-component reaction of benzil, aryl aldehydes and ammonium acetate for the synthesis 2-aryl-4,5-diphenyl-1H-imdazoles synthesis. To explore the high efficacy of the catalytic system the four-component cyclization of benzil, aryl aldehydes, ammonium acetate ...
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ژورنال
عنوان ژورنال: Analytical science advances
سال: 2023
ISSN: ['2628-5452']
DOI: https://doi.org/10.1002/ansa.202300012